103149-56-0Relevant academic research and scientific papers
Synthesis and Structures of Bicyclic Phosphoranes - Products Resulting from the Reaction of Hexafluoroacetone with Mercury Salts
Roesky, Herbert W.,Pogatzki, Volkmar W.,Dhathathreyan, Kaveripatnam S.,Thiel, Alfred,Schmidt, Hans Georg,et al.
, p. 2687 - 2697 (2007/10/02)
Hg(SCN)2 reacts with hexafluoroacetone (HFA) to give the cycloaddition product 1.Reaction of 1 with CF3SCl, ClSC2F4SCl, and Br2 leads to elimination of mercury with formation of the disulfanes 2, 3, and 4, respectively. 1 reacts with Ph2PCl to yield the b
