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103185-26-8

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103185-26-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 103185-26-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,3,1,8 and 5 respectively; the second part has 2 digits, 2 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 103185-26:
(8*1)+(7*0)+(6*3)+(5*1)+(4*8)+(3*5)+(2*2)+(1*6)=88
88 % 10 = 8
So 103185-26-8 is a valid CAS Registry Number.
InChI:InChI=1/C16H24/c1-15(2,3)4-5-16-9-12-6-13(10-16)8-14(7-12)11-16/h12-14H,6-11H2,1-3H3

103185-26-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-(3,3-dimethylbut-1-ynyl)adamantane

1.2 Other means of identification

Product number -
Other names Adamantyl-tert-butylacetylen

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:103185-26-8 SDS

103185-26-8Downstream Products

103185-26-8Relevant articles and documents

"One-step" alkynylation of adamantyl iodide with silver(I) acetylides

Pouwer, Rebecca H.,Williams, Craig M.,Raine, Alan L.,Harper, Jason B.

, p. 1323 - 1325 (2005)

(Chemical Equation Presented) Silver(I) acetylides allow one-step alkynylation of adamantyl iodide in yields ranging from 25 to 68%.

Small Rings, 90. - Peralkyl-Substituted Tetrahedranes

Maier, Guenther,Fleischer, Frank,Kalinowski, Hans-Otto

, p. 173 - 186 (2007/10/02)

Photolysis of the diazo compounds 4a, b generates adamantyltri-tert-butyltetrahedrane (9a) and tri-tert-butylisopropyltetrahedrane (9b), and the corresponding cyclobutadienes 10a, b.In contrast to tetrahedrane 9a, which results from an intramolecular addition in carbene 7a and also from photoisomerization of cyclobutadiene 10a, the only source for tetrahedrane 9b is the cheletropic cycloaddition of the carbenic center to the cyclopropene double bond in the photochemically produced carbene 7b.Tetrahedrane 9b is remarkable in its kinetic and thermal instability, which is caused by the reduced "corset effect" in this compoound.An additional access to this tetrahedrane is possible via the diazomethanes 34A and 34B.The pyridazines 17b and 41, which are formed by thermolysis of the diazo compounds 4b, 34A and 34B lead to the azetes 19 and 43.Last but not least 17b and 41 are interesting molecules themselves because of their inherent chirality. - Key Words: Tetrahedranes / Cyclobutadienes / Azetes / Cyclopropenyldiazomethanes / Pyridazines: chirality, ring inversion, valence isomers

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