103189-93-1Relevant academic research and scientific papers
CONCISE ASYMMETRIC SYNTHESIS OF (5S, 6S)- AEGINETOLIDE AND (5S)- DIHYDROACTINIDIOLIDE
Cain, C. M.,Simpkins, N. S.
, p. 3723 - 3724 (1987)
An asymmetric deprotonation reaction allows for short syntheses of the lactones (5S,6S)- Aeginetolide (1) and (5S)-Dihydroactinidiolide (2).
Asymmetric Deprotonation: A New Route to Chiral Compounds
Simpkins, Nigel S.
, p. 88 - 90 (2007/10/02)
Enantioselective deprotonation of symmetrically substituted ketones under kinetically controlled conditions provides chiral products in up to 74percent enantiomeric excess.
