1032008-57-3

Basic information

• Product Name: 3-(4-bromophenyl)-N,N-diisopropylprop-2-yn-1-amine
• Synonyms: 3-(4-bromophenyl)-N,N-diisopropylprop-2-yn-1-amine
• CAS NO: 1032008-57-3
• Molecular Weight: 294.235
• Mol File: 1032008-57-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-(4-bromophenyl)-N,N-diisopropylprop-2-yn-1-amine(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-bromophenyl)-N,N-diisopropylprop-2-yn-1-amine(1032008-57-3)
• EPA Substance Registry System: 3-(4-bromophenyl)-N,N-diisopropylprop-2-yn-1-amine(1032008-57-3)

Safety Data

• Hazardous Substances Data: 1032008-57-3(Hazardous Substances Data)

Upstream product

• 10342-97-9 N,N-diisopropylmethylamine 
• 934-95-2 1-bromo-4-(iodoethynyl)benzene 
• 50-00-0 formaldehyd 
• 766-96-1 4-bromo-1-ethynylbenzene 
• 108-18-9 diisopropylamine 

Relevant articles and documents

A highly efficient gold-catalyzed photoredox α-C(sp3)-H alkynylation of tertiary aliphatic amines with sunlight

A new α-C(sp3)-H alkynylation of unactivated tertiary aliphatic amines with 1-iodoalkynes as radical alkynylating reagents in the presence of [Au2(μ-dppm)2]2+ in sunlight provides propargylic amines. Based on mechanistic studies, a C-C coupling of an α-aminoalkyl radical and an alkynyl radical is proposed for the C(sp3)-C(sp) bond formation. The mild, convenient, efficient, and highly selective C(sp3)-H alkynylation reaction shows excellent regioselectivity and good functional-group compatibility. A scale-up to gram quantities is possible with sunlight used as a clean and sustainable energy source.