103223-89-8

Basic information

• Product Name: Carbamic acid, (1-oxo-2-propenyl)-, 1,1-dimethylethyl ester (9CI)
• Synonyms: Carbamic acid, (1-oxo-2-propenyl)-, 1,1-dimethylethyl ester (9CI)
• CAS NO: 103223-89-8
• Molecular Formula: C8H13NO3
• Molecular Weight: 171.19372
• Product Categories: N-BOC
• Mol File: 103223-89-8.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Carbamic acid, (1-oxo-2-propenyl)-, 1,1-dimethylethyl ester (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (1-oxo-2-propenyl)-, 1,1-dimethylethyl ester (9CI)(103223-89-8)
• EPA Substance Registry System: Carbamic acid, (1-oxo-2-propenyl)-, 1,1-dimethylethyl ester (9CI)(103223-89-8)

Safety Data

• Hazardous Substances Data: 103223-89-8(Hazardous Substances Data)

Upstream product

• 13641-97-9 acryloyl isocyanate 
• 24424-99-5 di-tert-butyl dicarbonate 
• 79-06-1 2-propenamide 

Relevant articles and documents

Alcohol-Substituted Vinyl Polymers for Stockpiling Hydrogen

To be used on a daily basis, hydrogen-storage materials need to stockpile hydrogen safely and to release it using only small amounts of energy. Chemically bonded hydrogen stored in a polymer is highly safe, enabling hydrogen to be stored under ambient conditions in a non-volatile, non-toxic, and nonflammable manner. The dehydrogenation reactions of alcohol-substituted vinyl polymers at mild temperatures was investigated. Poly(allyl alcohol) was dehydrogenated at 6595°C in the presence of an iridium complex catalyst to produce poly- (acrylic acid) due to the extremely low activation energy (10 kJ/mol) associated with the catalyst-specific cycle. Poly(allyl alcohol) demonstrated a hydrogen-storage density of 6.8 wt% by releasing two equivalents of hydrogen gas, which demonstrated that alcohol-substituted vinyl polymers could be used to stockpile hydrogen and release it under mild conditions.