103227-54-9

Basic information

• Product Name: 3-ethyl 1-tetradecen
• Synonyms: 3-ethyl 1-tetradecen
• CAS NO: 103227-54-9
• Molecular Weight: 224.43
• Mol File: 103227-54-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-ethyl 1-tetradecen(CAS DataBase Reference)
• NIST Chemistry Reference: 3-ethyl 1-tetradecen(103227-54-9)
• EPA Substance Registry System: 3-ethyl 1-tetradecen(103227-54-9)

Safety Data

• Hazardous Substances Data: 103227-54-9(Hazardous Substances Data)

Upstream product

• 103227-39-0 C₁₈H₃₂O₄ 

Downstream Products

• 69868-07-1 2-ethyl-tridecanoic acid 

Relevant articles and documents

SELECTIVE MIXED COUPLING OF CARBOXYLIC ACIDS (II). -PHOTOLYSIS OF UNSYMMETRICAL DIACYLPEROXIDES WITH ALKENYL-, HALO-, KETO-, CARBOXYL-GROUPS AND A CHIRAL α-CARBON. COMPARISON WITH THE MIXED KOLBE ELECTROLYSIS.

- Alkenoyl and functionalized alkanoyl dodecanoyl peroxides are prepared in 70 to 97 percent yield and photolyzed at -78 deg C.Thereby 4- to 10-alkenoyl and 4-alkynoyl peroxides afford good yields (56 - 68 percent) of unsymmetrical coupling products.Similarly α- to δ-haloalkanoyl, cholanoyl or 3- and 4-carboxyalkanoyl peroxides can be coupled (40 - 70 percent).The α-chiral diacyl peroxide 1s undergoes the photochemical coupling reaction with 80 percent retention of its configuration.The photolysis of diacyl peroxides at -78 deg C proves to be a favorable supplement of the Kolbe-electrolysis in cases, where the electrolysis fails or produces low yields.