1032476-07-5Relevant academic research and scientific papers
Synthesis of angularly fused carbocycles via tandem radical cyclization of α-carbonyl radicals
Prakash, Chandran,Mohanakrishnan, Arasambattu K.
scheme or table, p. 1535 - 1543 (2009/04/11)
An α-carbonyl radical cyclization approach towards the synthesis of angularly fused tricyclic systems is described. On reduction with tributyltin hydride, bromo ketones yield a α-carbonyl radical that undergoes successive 5-exo-dig/trig cyclizations, resu
A simple iodination protocol via in situ generated ICl using NaI/FeCl 3
Mohanakrishnan, Arasambattu K.,Prakash, Chandran,Ramesh, Neelamegam
, p. 3242 - 3247 (2007/10/03)
A novel iodination of silyl-enol ethers using hitherto unexplored NaI/FeCl3 system is reported. The procedure has been extended to the iodination of aromatic and hetero aromatic compounds.
