1032739-10-8Relevant articles and documents
Carbon tetrabromide-mediated carbon-sulfur bond formation via a sulfenyl bromide intermediate
Tan, Jing,Liang, Fushun,Wang, Yeming,Cheng, Xin,Liu, Qun,Yuan, Hongjuan
body text, p. 2485 - 2488 (2009/05/26)
(Chemical Equation Presented) In the presence of carbon tetrabromide, a variety of dithiocarbamates, xanthates, dithioesters, and thioethers were prepared in one pot by reacting the corresponding dithioic acids or thiols with active methylene compounds/indole derivatives under mild conditions. The formation of a sulfenyl bromide intermediate is proposed as the key step, which initiates the C-S bond formation.