103277-81-2Relevant academic research and scientific papers
An Investigation of the Inherent Chiral Induction Ability of Axially Chiral 1,1'-Binaphthalene Framework in the Prelog's Atrolactic Acid Synthesis
Tamai, Yasufumi,Nakano, Tomoyuki,Miyano, Sotaro
, p. 807 - 808 (2007/10/02)
In the Prelog's atrolactic acid synthesis using 2'-substituted 1,1'-binaphthalen-2-ols as the chiral auxiliaries, the sense of the diastereoselection could not solely be determined by the helicity of the 1,1'-binaphthalene framework.A revised steric model
Reinvestigation of the Addition of Methylmagnesium Iodide to the Benzoylformate of Enantiomerically Pure 1,1'-Binaphthyl-2-ol Prepared by Enzymatic Kinetic Resolution
Tamai, Yasufumi,Nakano, Tomoyuki,Koike, Sinji,Kawahara, Kan,Miyano, Sotaro
, p. 1135 - 1136 (2007/10/02)
A lipase from pseudomonas was found to catalyze almost completely ena tioselective hydrolysis of the valerate of racemic 1,1'-binaphthyl-2-ol (1).The Prelog's atrolactic acid synthesis by use of (aR)-1 induced S-chirality with much lower levels of optical
