1032821-08-1Relevant articles and documents
An uncommon multicentered ZnI-ZnIbond-based MOF for CO2fixation with aziridines/epoxides
Cao, Chun-Shuai,Shi, Ying,Xu, Hang,Zhao, Bin
, p. 7537 - 7540 (2021)
A novel cluster-based MOF with uncommon multicentered ZnI-ZnIbonds {[K1.2Na2.8ZnI8(HL)12]·4H2O}n(HL = tetrazole monoanion) (1) was synthesized, which showed higher stability than the reported ZnI-ZnIbonded compounds. Moreover,1can effectively and circularly catalyze the cyclization of CO2and aziridines or epoxides with five substituent groups. Importantly, this is the first time that the catalytic properties of MOFs with multicentered metal-metal bonded clusters as the catalyst have been studied.