1032929-68-2

Upstream product

• 174894-87-2 4-(4″-methylphenyl)-6-phenyl-2,2′-bipyridine 

Downstream Products

• 1385756-89-7 4-[(4-(4,4'-bipyridinium-1-yl)methyl)phenyl]-6-phenyl-2,2'-bipyridine bromate 
• 1500082-35-8 C₄₁H₃₂N₂P⁽¹⁺⁾*Br^(1-) 
• 1032929-70-6 C₉₀H₈₈N₄O₄ 
• 1251830-35-9 25,27-bis[methoxy(4-phenyl)-(6'-phenyl-2',2''-bipyridine)]-26,28-dihydroxycalix[4]arene 

Relevant academic research and scientific papers

Novel 2,2′-bipyridine-modified calix[4]arenes: Ratiometric fluorescent chemosensors for Zn2+ ion

Two calix[4]arene derivatives with modified bipyridine as binding sites have been designed and synthesized. Compounds 1 and 2 are the first 2,2′-bipyridine-modified calix[4]arene-based sensors that can detect Zn2+ selectively with respect to ratiometric fluorescent changes and red shift. A binuclear complex structure has been demonstrated in the binding modes of 1-Zn2+ and 2-Zn2+ complexes.

Organoplatinum(II) complexes with chromophore-acceptor dyad studied by ultrafast time-resolved absorption spectroscopy

The photoinduced ET reaction from PtIIchromophore to viologen acceptor in a new ultrafast time-resolved absorption spectroscopy has been reported. Photoinduced electron-transfer (ET) reactions are fundamental steps in photosynthesis, and which have led to extensive investigations into charge-separated species in artificial mimics. The development of the absorption maxima at 395 and 605 nm could be attributed to the formation of methyl viologen radical cation as a result of oxidative decomposition of TEOA. The back ET reaction rate constants of the two platinum (II) systems are slower than the forward electron-transfer reactions, despite the large driving force. Efforts to harness the slow back ET reactions of PtII chromophore acceptor systems for light-induced multi-electron-transfer catalysis are in progress.

Synthesis, crystal structures, one/two-photon optical properties and bioimaging application of two organic molecules with D-A and D-π-A models containing 6-phenyl-2,2′-bipyridine

Two novel organic compounds with D-A (L1) and D-π-A (L2) models containing 4-(N,N-dipropylamino)phenyl [donor group (D)] and 6-phenyl-2,2′-bipyridine [acceptor (A)] groups were synthesized and characterized by IR, 1H NMR, 13C NMR, MS and single crystal X-ray diffraction. Their photophysical properties were systematically investigated using both experiments and theoretic calculations. It was found that the two-photon action cross-section (δΦ) of the D-π-A model molecule (δΦL2 = 119 GM) was approximately three times larger than that of the D-A type molecule (δΦL1 = 43 GM). Furthermore, their cytotoxicity and applications in bioimaging were determined. The results showed that L1 and L2 could be used as cytoplasmic dyes with high stability and low cytotoxicity.