103305-01-7Relevant academic research and scientific papers
COMPOUNDS WITH (PERFLUOROALKYL) FLUOROHYDROGENPHOSPHATE ANIONS
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Page/Page column 15, (2012/10/23)
The present invention relates to a process for the preparation of compounds with (perfluoroalkyl)fluorohydrogenphosphate anion, and to compounds containing (perfluoroalkyl)fluorohydrogenphosphate anion and to the use thereof.
PROCESS FOR THE PREPARATION OF BIS(FLUOROALKYL)PHOSPHINIC ACID OR FLUOROALKYLPHOSPHONIC ACID
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Page/Page column 3-4, (2011/06/23)
The invention relates to a process for the preparation of bis(fluoroalkyl)phosphinic acid and/or fluoroalkylphosphonic acid by reaction of, monofluoroalkyltetrafluorophosphorane bis(fluoroalkyl)trifluorophosphorane or tris(fluoroalkyl)difluorophosphorane with water.
Reaction of perfluoroalkyl Grignard reagents with phosphorus trihalides: A new route to perfluoroalkyl-phosphonous and-phosphonic acids
Hosein, Adil I.,Le Goff, Xavier F.,Ricard, Louis,Caffyn, Andrew J. M.
experimental part, p. 1484 - 1490 (2011/04/23)
The reaction of perfluoroalkyl Grignard reagents with phosphorus(III) halides was explored. In the process a new convenient, one-pot, high yield method for the synthesis of (perfluoroalkyl)phosphonic acids has been developed. Perfluoroalkyl Grignard reagents react with phosphorus trichloride or phosphorus tribromide to form (perfluoroalkyl)phosphonous dihalides. Hydrolysis gives the corresponding (perfluoroalkyl)phosphonous acids. Oxidation of the phosphonous acids with H2O2 produces (perfluoroalkyl) phosphonic acids in 60-78% overall yields, based on the corresponding perfluoroalkyl iodide. The X-ray crystal structures of the toluidinium salts, [MeC6H4NH3]2[C2F 5PO3] and [MeC6H4NH 3][C8F17P(O)2OH], are reported.
Perfluoroalkanoic hydroformed mono-, bis (perfluorolefin alkyl) acid synthesis of salt and perfluorolefin alkylphosphonic
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Page/Page column 20, (2008/06/13)
The present invention relates to a process for the preparation of monohydroperfluoroalkanes, bis(perfluoroalkyl)phosphinates and perfluoroalkylphosphonates which comprises at least the treatment of at least one perfluoroalkylphosphorane with at least one base in a suitable reaction medium.
