1033221-70-3Relevant academic research and scientific papers
Biaryl formation from 5-(2-bromobenzyl)-substituted piperidin-2-ones via palladacycles
Satyanarayana, Gedu,Maier, Martin E.
supporting information; experimental part, p. 2361 - 2364 (2009/05/27)
(Chemical Equation Presented) The reaction of piperdin-2-ones with a 2-bromobenzyl substituent in the 5-position in the presence of a palladium catalyst leads to biaryl compounds. Their formation can be explained via initial C-H insertion of the aryl pall
Unsymmetrical biaryls by palladium-catalyzed coupling of aryl halides with internal reduction
Satyanarayana, Gedu,Maier, Martin E.
experimental part, p. 5543 - 5552 (2009/05/11)
Aryl bromides containing a (1,4,5,6-tetrahydro-6-oxopyridin-3-yl)methyl substituent can be coupled with aryl halides yielding unsummetrical biaryls. In the course of this process, the cyclic enamide is oxidized to the 2(1H)-pyridinone. The reaction procee
