103352-28-9

Basic information

• Product Name: W(OC₆H₃(CH₃)2)2Cl(CH₂C(CH₃)3)(CHC(CH₃)3)(O(C₂H₅)2)
• CAS NO: 103352-28-9
• Molecular Weight: 677.02
• Mol File: 103352-28-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: W(OC₆H₃(CH₃)2)2Cl(CH₂C(CH₃)3)(CHC(CH₃)3)(O(C₂H₅)2)(CAS DataBase Reference)
• NIST Chemistry Reference: W(OC₆H₃(CH₃)2)2Cl(CH₂C(CH₃)3)(CHC(CH₃)3)(O(C₂H₅)2)(103352-28-9)
• EPA Substance Registry System: W(OC₆H₃(CH₃)2)2Cl(CH₂C(CH₃)3)(CHC(CH₃)3)(O(C₂H₅)2)(103352-28-9)

Safety Data

• Hazardous Substances Data: 103352-28-9(Hazardous Substances Data)

Upstream product

• 157477-68-4 WCl₄{O-2,6-(CH₃)2C₆H₃}2 
• 67608-37-1 Mg(CH₂C(CH₃)3)2 * dioxane 

Relevant articles and documents

Synthesis and Catalytic Properties of W(OAr)2Cl2(CHCMe3)(OR2) and W(OAr)2Cl(CHCMe3)(CH2CMe3)(OR2) (Ar = 2,6-disubstituted phenyl; R = Et or i-Pr), New Uni-component Catalysts for Metathesis of Acyclic and Cyclic Olefins, with or without Functional Groups

The synthesis of W(OAr)2Cl(CHR)(CH2R1)(OR22) (Ar = 2,6-disubstituted phenyl; R2 = Et or i-Pr) illustrates one of the first examples of a well defined, Lewis acid-free, homogeneous olefin metathesis catalyst, for which the activity and stereoselectivity can be governed by the nature of the aryloxide ligands and of the co-ordinated ether and which shows a wide range of potential applications.