103366-90-1

Basic information

• Product Name: Propanedioic acid, [(2-methylpropyl)imino]-, dimethyl ester
• CAS NO: 103366-90-1
• Molecular Formula: C9H15NO4
• Mol File: 103366-90-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Propanedioic acid, [(2-methylpropyl)imino]-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propanedioic acid, [(2-methylpropyl)imino]-, dimethyl ester(103366-90-1)
• EPA Substance Registry System: Propanedioic acid, [(2-methylpropyl)imino]-, dimethyl ester(103366-90-1)

Safety Data

• Hazardous Substances Data: 103366-90-1(Hazardous Substances Data)

Upstream product

• 39520-24-6 Isobutylmalonsaeure-dimethylester 
• 103366-89-8 Azidoisobutylmalonsaeure-dimethylester 

Downstream Products

• 3182-85-2 N-Isobutylglycin 

Relevant articles and documents

Rearrangement of Azidomalonic Esters

Dimethyl azidomalonate (4) is photolyzed under loss of nitrogen and rearrangement of one methoxycarbonyl group to form the mixture of Z and E isomers of the α,β-unsaturated amino acid esters 8 and 9.On photolysis of isopropyl- and isobutylazidomalonates 10 migration of the alkyl group is observed exclusively.The (alkylimino)malonates 14 so formed have been hydrogenated and hydrolyzed to give the N-alkylglycine derivatives 16.