103392-94-5Relevant articles and documents
Stabilization of excited state using through-space interaction between independent π-systems mediated by a peri-substituted hydroxy group in 1-arylnaphthalenes: Unexpected blue emission of 1,3,5-tris(peri-hydroxynaphthyl) benzene
Nakajima, Hideto,Yasuda, Makoto,Shimizu, Kenji,Toyoshima, Naomi,Tsukahara, Yasunori,Kobayashi, Takao,Nakamura, Shinichiro,Chiba, Kouji,Baba, Akio
, p. 1118 - 1129 (2011)
The control of photoluminescence wavelength is important for the design of emitting materials, and compounds bearing arylaryl bonds are considered to be useful candidates for the synthesis of these materials. However, the biaryl system lacks an efficient
Chiral 2-(2-hydroxyaryl)alcohols (HAROLs) with a 1,4-diol scaffold as a new family of ligands and organocatalysts
Dilek, ?mer,Tezeren, Mustafa A.,Tilki, Tahir,Ertürk, Erkan
, p. 268 - 286 (2017/12/06)
Efficient and modular syntheses of chiral 2-(2-hydroxyaryl)alcohols (HAROLs), novel 1,4-diols carrying one phenolic and one alcohol hydroxyl group, have been developed which led to generation of a small library of structurally diverse HAROLs in enantiomerically pure form. Of the different HAROLs examined, a HAROL based on the indan backbone exhibited the highest activity and enantioselectivity in the 1,2-addition of certain organometallic compounds to aldehydes in the presence of Ti(OiPr)4 (up to 97% y, 88% ee) and performed as a hydrogen-bond donor organocatalyst in the Morita-Baylis-Hillman reaction, promoted by trialkylphosphines.
