1034001-51-8

Basic information

• Product Name: [RuCl(p-cymene)((R)-tolbinap)]Cl
• Synonyms: [RuCl(p-cymene)((R)-tolbinap)]Cl;[RuCl(p-cymene)((R)-tolbinap)]Cl [RuCl(p-cymene)((R)-tolbinap)]Cl
• CAS NO: 1034001-51-8
• Molecular Formula: C₅₈H₅₄Cl₂P₂Ru
• Molecular Weight: 984.972882
• EINECS: -0
• Mol File: 1034001-51-8.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: [RuCl(p-cymene)((R)-tolbinap)]Cl(CAS DataBase Reference)
• NIST Chemistry Reference: [RuCl(p-cymene)((R)-tolbinap)]Cl(1034001-51-8)
• EPA Substance Registry System: [RuCl(p-cymene)((R)-tolbinap)]Cl(1034001-51-8)

Safety Data

• Hazardous Substances Data: 1034001-51-8(Hazardous Substances Data)

Usage

Uses

Used in Catalysis Applications:
[RuCl(p-cymene)((R)-tolbinap)]Cl is used as a catalyst in various chemical reactions due to the reactivity of the ruthenium center and the nature of the ligands. [RuCl(p-cymene)((R)-tolbinap)]Cl's catalytic properties can be utilized in a wide range of applications, including the synthesis of pharmaceuticals, agrochemicals, and fine chemicals.
Used in Asymmetric Catalysis:
[RuCl(p-cymene)((R)-tolbinap)]Cl is used as a chiral catalyst in asymmetric catalysis for the enantioselective synthesis of chiral compounds. The chiral nature of the (R)-tolbinap ligand in the complex allows for the selective formation of one enantiomer over the other, which is crucial in the production of enantiomerically pure compounds with specific biological activities.
Used in Organometallic Chemistry:
[RuCl(p-cymene)((R)-tolbinap)]Cl is used as a building block in the synthesis of other organometallic compounds. [RuCl(p-cymene)((R)-tolbinap)]Cl's unique structure and properties make it a valuable precursor for the preparation of more complex organometallic species with potential applications in various fields, such as homogeneous catalysis, materials science, and medicinal chemistry.
Used in Environmental Applications:
[RuCl(p-cymene)((R)-tolbinap)]Cl can be used as a catalyst in environmental remediation processes, such as the degradation of pollutants and the reduction of heavy metal ions. [RuCl(p-cymene)((R)-tolbinap)]Cl's catalytic properties can facilitate the transformation of harmful substances into less toxic or more easily removable forms, contributing to a cleaner and safer environment.
Used in Energy Applications:
[RuCl(p-cymene)((R)-tolbinap)]Cl can be employed as a catalyst in energy-related processes, such as the production of hydrogen from water splitting or the conversion of carbon dioxide into useful chemicals. [RuCl(p-cymene)((R)-tolbinap)]Cl's ability to facilitate challenging chemical transformations can contribute to the development of sustainable energy solutions and the reduction of greenhouse gas emissions.

Upstream product

• 153305-67-0 (+)-(R)-2,2'bis(di-para-tolylphosphanyl)-1,1'binaphthyl 

Downstream Products

• 112065-78-8 diacetato[(R)-(+)-2,2-bis(di-p-tolylphosphono)-1,1′?binaphthyl]ruthenium(II) 

Relevant articles and documents

Synthesis of New Cationic BINAP-Ruthenium(II) Complexes and their Use in Asymmetric Hydrogenation

Reaction of 2 (1) and (S)-BINAP gives cationic BINAP-ruthenium complexes of the formula Y (2) (X = Cl, Br, and I; Y = Cl, Br, I, BF4, and BPh4; arene = C6H6 and p-MeC6H4CHMe2) which are efficient catalyst precursors for enantioselective hydrogenation of various prochiral alkenic and ketonic substrates ; a crystal structure of (2) (with X = Cl, Y = BF4) was obtained.