1034001-51-8 Usage
General Description
[RuCl(p-cymene)((R)-tolbinap)]Cl is a chemical compound that consists of a ruthenium (Ru) atom coordinated to a pentamethylcyclopentadienyl ligand (p-cymene), a chiral N-heterocyclic carbene ligand ((R)-tolbinap), and a chloride ion. The coordination geometry around the ruthenium atom is octahedral, and the complex is overall charged due to the presence of the chloride ion. [RuCl(p-cymene)((R)-tolbinap)]Cl has potential applications in catalysis due to the nature of the ligands and the reactivity of the ruthenium center. Additionally, the chiral nature of the ligands may give rise to interesting and useful properties for asymmetric catalysis. Overall, [RuCl(p-cymene)((R)-tolbinap)]Cl is a complex with potential for various applications in the field of organometallic chemistry and catalysis.
Check Digit Verification of cas no
The CAS Registry Mumber 1034001-51-8 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,3,4,0,0 and 1 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 1034001-51:
(9*1)+(8*0)+(7*3)+(6*4)+(5*0)+(4*0)+(3*1)+(2*5)+(1*1)=68
68 % 10 = 8
So 1034001-51-8 is a valid CAS Registry Number.
1034001-51-8Relevant articles and documents
Synthesis of New Cationic BINAP-Ruthenium(II) Complexes and their Use in Asymmetric Hydrogenation
Mashima, Kazushi,Kusano, Koh-hei,Ohta, Tetsuo,Noyori, Ryoji,Takaya, Hidemasa
, p. 1208 - 1210 (2007/10/02)
Reaction of 2 (1) and (S)-BINAP gives cationic BINAP-ruthenium complexes of the formula Y (2) (X = Cl, Br, and I; Y = Cl, Br, I, BF4, and BPh4; arene = C6H6 and p-MeC6H4CHMe2) which are efficient catalyst precursors for enantioselective hydrogenation of various prochiral alkenic and ketonic substrates ; a crystal structure of (2) (with X = Cl, Y = BF4) was obtained.
