1034137-23-9Relevant academic research and scientific papers
Expanded ring N-heterocyclic carbene complexes of zero valent platinum dvtms (divinyltetramethyldisiloxane): Highly efficient hydrosilylation catalysts
Dunsford, Jay J.,Cavell, Kingsley J.,Kariuki, Benson
experimental part, p. 188 - 194 (2011/02/16)
The synthesis and characterisation of a series of new 6- and 7-membered NHC (N-heterocyclic carbene) complexes 7-12 of zero valent platinum dvtms (divinyltetramethyldisiloxane), [Pt(NHC)(dvtms)] are reported. A number of the complexes were investigated as catalyst precursors in the hydrosilylation of a range of unsaturated substrates, including alkynes, alkenes and a ketone with triethylsilane and bis(trimethylsiloxy)methylsilane (MD'M), at low catalyst loading (0.005 mol %); in general, the activity, and the selectivity for 1-functionalised product was found to be high.
Expanded ring N-heterocyclic carbenes: A comparative study of ring size in palladium (0) catalysed Mizoroki-Heck coupling
Dunsford, Jay J.,Cavell, Kingsley J.
supporting information; experimental part, p. 9131 - 9135 (2011/10/17)
The synthesis and characterisation of a range of new 6- and 7-membered expanded ring N-heterocyclic carbene (NHC) complexes of zero valent palladium dvtms (divinyltetramethyldisiloxane) 8-14 is reported, with the first comparative catalytic study probing
