1034192-69-2Relevant academic research and scientific papers
TEMPO/NaIO4-SiO2: A catalytic oxidative rearrangement of tertiary allylic alcohols to β-substituted α,β-unsaturated ketones
Shibuya, Masatoshi,Tomizawa, Masaki,Iwabuchi, Yoshiharu
supporting information; scheme or table, p. 4715 - 4718 (2009/05/31)
(Chemical Equation Presented) The novel catalytic method for the oxidative rearrangement of tertiary allylic alcohols to β-substituted α,β-unsaturated ketones is described. TEMPO/NaIO4-SiO 2 causes facile and efficient oxidative rearrangement of various acyclic substrates as well as medium-sized and macrocyclic substrates.
Oxidative rearrangement of tertiary allylic alcohols employing oxoammonium salts
Shibuya, Masatoshi,Tomizawa, Masaki,Iwabuchi, Yoshiharu
, p. 4750 - 4752 (2008/09/20)
(Chemical Equation Presented) Practical and highly efficient methods for oxidative rearrangement of tertiary allylic alcohols to β-substituted α,β-unsaturated carbonyl compounds employing oxoammonium salts are described. The methods developed are applicable to acyclic substrates as well as medium membered ring substrates and macrocyclic substrates. The counteranion of the oxoammonium salt plays crucial roles on this oxidative rearrangement.
