103421-08-5

Basic information

• Product Name: (1R,4S,5S)-4-Isopropyl-3-oxa-bicyclo[3.2.0]heptan-2-one
• CAS NO: 103421-08-5
• Molecular Weight: 154.209
• Mol File: 103421-08-5.mol

Chemical Properties

• CAS DataBase Reference: (1R,4S,5S)-4-Isopropyl-3-oxa-bicyclo[3.2.0]heptan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4S,5S)-4-Isopropyl-3-oxa-bicyclo[3.2.0]heptan-2-one(103421-08-5)
• EPA Substance Registry System: (1R,4S,5S)-4-Isopropyl-3-oxa-bicyclo[3.2.0]heptan-2-one(103421-08-5)

Safety Data

• Hazardous Substances Data: 103421-08-5(Hazardous Substances Data)

Upstream product

• 4462-96-8 cis-1,2-cyclobutane dicarboxylic anhydride 
• 920-39-8 isopropylmagnesium bromide 

Relevant articles and documents

REDUCTION DES ANHYDRIDES BICYCLIQUES CONDENSES PAR LE BROMURE DE CYCLOPENTYLMAGNESIUM

Greatly different product distributions were observed in the reactions of cyclopentyl- and isopropylmagnesium bromides with cyclohexane-, cyclohex-4-ene- and cyclobutane-1,2 dicarboxylic anhydrides.Cyclopentylmagnesium bromide yielded reduction products with high stereoselectivity whereas the isopropylmagnesium bromide provided the corresponding trans diastereomeric ketoacids via an addition enolization process.