1034287-04-1Relevant articles and documents
Sequential Seyferth-Gilbert/CuAAC reactions: Application to the one-pot synthesis of triazoles from aldehydes
Luvino, Delphine,Amalric, Camille,Smietana, Michael,Vasseur, Jean-Jacques
, p. 3037 - 3041 (2007)
A reliable and operationally simple one-pot reaction for a one-carbon homologation of various aldehydes followed by a Cu-catalyzed azide-alkyne 1,3-dipolar cycloaddition (CuAAC) is reported. 1,4-Disubstituted 1,2,3-triazoles are obtained in good to excellent yields from a variety of readily available aldehydes without the need for isolation of the alkyne intermediates. The reaction has a broad scope, allows the formation of new bioconjugates and is applied for the synthesis of new boronic acid based fluorescent sensors. Georg Thieme Verlag Stuttgart.
Synthesis and electroluminescence properties of white-light single polyfluorenes with high-molecular weight by click reaction
Lo, Chih-Nan,Hsu, Chain-Shu
, p. 3355 - 3365 (2012/05/04)
We reported a new way to synthesize single-chain white light-emitting polyfluorene (WPF) with an increased molecular weight using azide-alkyne click reaction. Four basic polymers with specific end-capping, which exhibited high-glass transition temperatures (Tg > 100 °C) and excellent thermal stability, were used as foundations of the WPF's synthesis; a blue-light polymer (PFB2) end-capped with azide groups can easily react with acetylene end-capped polymers (PFB1, PFG1, and PFR1, which are emitting blue-, green- and red-light, respectively) to form triazole-ring linkages in polar solvents such as N,N-dimethylforamide/toluene co-solvent at moderate temperature of 100 °C, even without metal-catalyst. Several WPFs that consist of these four basic polymers in certain ratios were derived, and the polymer light-emitting diode device based on the high-molecular weight WPF was achieved and demonstrated a maximum brightness of 7551 cd/m2 (at 12.5 V) and a maximum yield of 5.5 cd/A with Commission Internationale de l'Eclairage coordinates of (0.30, 0.33) using fine-tuned WPF5 as emitting material.