103432-35-5Relevant academic research and scientific papers
The Chemistry of Dinitrogen Residues. Part 3. Hydrazido(2-)-derivatives of Titanium(IV). X-Ray Crystal Structure of 2>
Hughes, David L.,Latham, Ian A.,Leigh, G. Jeffery
, p. 393 - 398 (2007/10/02)
The preparations of 1,2-hydrazide(2-) and 1,1-hydrazide(2-) complexes of titanium(IV) are described.The 1H n.m.r. spectra of dinuclear 1,1-disubstituted hydrazide(2-) complexes, such as 2>, are anomalous, but can be explained on the basis of an X-ray structure analysis which shows that one hydrazide forms a symmetrical bridge whereas the other is both bridging and bound side-on to one of the titaniums.
