103439-91-4Relevant academic research and scientific papers
Kinetics of the reaction of sodium arylthiolates with nitro-carboxybenzyl halide derivatives
Hamed, Ezzat A.,El-Bardan, Ali A.,El-Mallah, Nabila M.
, p. 283 - 289 (2007/10/03)
The rate constants for the reactions of 4-halomethyl-3-nitrobenzoic acids, the nonnitro derivatives, and their ethyl esters with arylthiolates were measured at different temperatures. It was found that the retardation in rate constants compared to benzyl halides is due to the electrostatic repulsion between the electronegative substituents (COO- and/or NO2) in the substrates and thiolate ions Good correlations between log K2 values of the acids and carbon basicities of thiolates were found while log k2 values of the esters show good straight lines with Hammett a constants, pKa. and carbon basicities of arylthiolates.
Synthesis and Spectral Studies of Some New Sulfides and Sulfones
Kassem, Ahmed A.,El-Bardan, All A.
, p. 496 - 498 (2007/10/02)
Sixteen new substituted benzylphenyl sulfides and sulfones have been synthesized.Their structures were proved by IR, (1)H NMR, and mass spectra.A linear relationship between δ-values of the benzylic protons and ?-(Hammet) values of the phenyl substituents
