103477-04-9Relevant articles and documents
Catalyst-free and stereoselective synthesis of N,N-bicyclic pyrazolidinone derivatives
Yang, Desuo,Fan, Mingjin,Zhu, Haiyun,Guo, Yaning,Guo, Jiangtao
, p. 1325 - 1332 (2013)
A catalyst-free and stereoselective cycloaddition of pyrazolidin-3-one- derived azomethine imine to trans-β-nitrostyrene is described, which allows versatile, efficient and highly enantioselective synthesis of N,N-bicyclic pyrazolidinone derivatives. Georg Thieme Verlag Stuttgart, New York.
ARE ANY NON-STEREOSPECIFIC 1,3-DIPOLAR CYCLOADDITIONS KNOWN? A REVISION
Huisgen, Rolf,Weinberger, Rudolf
, p. 5119 - 5122 (1985)
The cycloaddition of 1-benzylidenepyrazolid-3-one betaine to (E)-β-nitrostyrene, which has been claimed to furnish 15-30percent non-stereospecific product, revealed stereospecificity up to 99.92percent in a renewed study; (Z)-β-nitrostyrene stereoisomerizes under the influence of the 1,3-dipole
1,3-DIPOLAR CYCLOADDITION OF PYRAZOLID 3-ONE AZOMETHINIMINES AND E-β-NITROSTYRENE - ELUCIDATION OF THE GENERATION OF SEEMINGLY "NON CISOID" ADDUCTS
Dorn, Helmut
, p. 5123 - 5126 (2007/10/02)
Highly polar 1,3-dipoles like pyrazolid-3-one azomethinimines stereospecifically add polar dipolarophiles.A suggested "non cisoid" adduct of E-β-nitrostyrene is generated by epimerization at C-2, catalysed by Kieselgel 40 MERCK and small amounts of pyrazolid-3-one.