1034979-67-3Relevant academic research and scientific papers
Base-Promoted C-O Bond Cleavage of Primary Alcohols by Iridium(III) Porphyrin Chloride
Bian, Yongjun,Qu, Xingyu,Chan, Kin Shing
supporting information, p. 1376 - 1383 (2020/04/20)
Various Ir(por)-benzyls and Ir(por)-alkyls (por = porphyrinato dianion ligand) were successfully synthesized with benzyl and 1° alkyl alcohols by C-O bond cleavage with Ir(ttp)(CO)Cl (ttp = 5,10,15,20-tetraphenylporphyrinato dianion) in alkaline media. The alkylation products were afforded in up to 92% yields. Mechanistic investigations suggest that both the Ir(ttp)- anion and Ir(ttp)H are key intermediates via a hydrogen-borrowing pathway.
Base-promoted selective activation of benzylic carbon-hydrogen bonds of toluenes by iridium(III) porphyrin
Cheung, Chi Wai,Chan, Kin Shing
, p. 3043 - 3055 (2009/02/05)
K2CO3 and NaOPh promoted the rate of benzylic carbon-hydrogen bond activation (BnCHA) of toluenes with iridium(III) porphyrin carbonyl chloride (Ir(ttp)Cl(CO)) to give iridium porphyrin benzyls in high yields. Mechanistic studies sug
