103499-75-8Relevant articles and documents
Endo-Selective Insertion by Norcaranylidene Carbenoid into the α-C-H Bond of Alkoxides: Evidence of a Hydride Abstraction-Recombination Mechanism
Oku, Akira,Yamaura, Yasunari,Harada, Toshiro
, p. 3730 - 3732 (2007/10/02)
A hydride abstraction-recombination mechanism in the insertion of the α-C-H bond of alkoxides by norcaranylidene carbenoid is proposed on the basis of the preferential endo stereoselectivity at the carbenic carbon of the insertion products