103517-76-6Relevant academic research and scientific papers
Synthesis of trans-1,4-Bis-2-butenes
Richter, Wolf Juergen,Neugebauer, Brigitte
, p. 1059 - 1060 (1985)
The reaction of chlorodimethylorganosilanes -2-butenes in 55-88percent yield.The amount of (Z)-isomer ranges f
Formation of 1,4-Disilyl-2-butenes from Vinyl Grignard Reagent and Chlorosilanes Catalyzed by a Titanocene Complex
Watabe, Hiroyasu,Terao, Jun,Kambe, Nobuaki
, p. 1733 - 1735 (2001)
(matrix presented) Symmetrical 1,4-disilyl-2-butenes 1 have been prepared by the reaction of vinyl Grignard reagent with chlorosilanes. This reaction proceeds efficiently in the presence of a catalytic amount of titanocene dichloride at 0 °C in THF. When dichlorodiphenylsilane was used, 1,1-diphenyl-1-silacyclo-3-pentene 2 was obtained in a good yield.
