1035223-30-3Relevant academic research and scientific papers
NMR and X-ray diffraction analysis of 3-thioamido-5-phosphono-1-cyclohexene derivatives: Conformational and stereochemical assignments
Monbaliu, Jean-Christophe,Tinant, Bernard,Marchand-Brynaert, Jacqueline
, p. 113 - 118 (2008)
Reaction of N-(dienyl)-4-(R)-phenyloxazolidin-2-thione (1) with 1-diethoxyphosphoryl-1-buten-3-one (2a), methyl 3-(diethoxyphosphoryl)acrylate (2b) and 3-(diethoxyphosphoryl)acrylonitrile (2c) furnished the [4 + 2] cycloadducts 3a, 3b and 3c, respectively
(R)-4-phenyloxazolidin-2-thione: an efficient chiral auxiliary for [4+2] cycloaddition of 1-aminodiene and activated phosphonodienophiles
Monbaliu, Jean-Christophe,Robiette, Rapha?l,Peeters, Daniel,Marchand-Brynaert, Jacqueline
body text, p. 1314 - 1317 (2009/06/28)
A theoretical model for the facial selectivity of N-dienyl oxazolidin-2-(thi)one and thiazolidin-2-thione 2a-c is presented. Our analysis provides a clear understanding of factors controlling stereoselectivity in reaction of these dienes, and allows predi
