103593-61-9Relevant academic research and scientific papers
A NOVEL SYNTHETIC METHOD OF OPTICALLY PURE α-SUBSTITUTED ALDEHYDE ACETALS BY USE OF REDUCTIVE 1,2-REARRANGEMENT
Honda, Yutaka,Sakai, Mitsuru,Tsuchihashi, Gen-ichi
, p. 1153 - 1156 (2007/10/02)
A new reductive 1,2-rearrangement of aryl (or alkenyl) groups of α-sulfonyloxy acetals to give the title compounds was developed by using the combination of i-Bu2AlH and Et3Al, and this method was applied to the synthesis of optically pure (R)-(-)-α-curcu
