1035948-08-3Relevant academic research and scientific papers
Natural and unnatural A-seco terpenes from pulegone: Synthesis of galbanic acid and marneral revisited
Corbu, Andrei,Aquino, Maurizio,Perez, Manuel,Gandara, Zoila,Arseniyadis, Simeon
scheme or table, p. 6386 - 6392 (2011/03/19)
We describe herein an improved chiral-pool strategy for assembling the core structure 3 (both antipodes) of various Aseco terpenoids that have allowed us to prepare natural galbanic acid [(-)-1] from (S)-(-)-pulegone [(-)-2]. Furthermore, we were able to
Total synthesis and structural confirmation of ent-galbanic acid and marneral
Corbu, Andrei,Perez, Manuel,Aquino, Maurizio,Retailleau, Pascal,Arseniyadis, Simeon
supporting information; experimental part, p. 2853 - 2856 (2009/05/27)
(Chemical Equation Presented) By capitalizing on a highly selective Claisen rearrangement, ent-galbanic acid 1 and (+)-marneral 2 have been synthesized. The relative configurations of (+)-1 and (+)-2 were unambiguously established by X-ray crystallographi
