103597-22-4

Upstream product

• 925-90-6 ethylmagnesium bromide 
• 40653-15-4 methyl 2,3,4-tri-O-benzyl-α-D-gluco-hexodialdo-1,5-pyranoside 
• 74-86-2 acetylene 
• 103597-18-8 methyl-2,3,4-tri-O-benzyl-7,7,8,8-tetradehydro-7,8-dideoxy-α-D-glycero-D-gluco-octopyranoside 
• 83051-88-1 methyl 6-aldehydo-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 161147-32-6 (S)-3-Trimethylsilanyl-1-((2R,3S,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-prop-2-yn-1-ol 
• 113421-07-1 methyl 2,3,4-tri-O-benzyl-7,7,8,8-tetradehydro-7,8-dideoxy-6-O-(p-nitrobenzoyl)-β-L-glycero-D-gluco-octopyranoside 

Downstream Products

• 113421-04-8 methyl-6-O-benzoyl-2,3,4-tri-O-benzyl-7,7,8,8-tetradehydro-7,8-dideoxy-α-D-glycero-D-gluco-octopyranoside 
• 103597-23-5 methyl 2,3,4-tri-O-benzyl-6,7-dideoxy-L-glycero-α-D-gluco-oct-7-ene-1,5-pyranoside 
• 161147-36-0 Methyl 6-azido-2,3,4-tri-O-benzyl-6,7,8-trideoxy-D-glycero-α-D-gluco-oct-7-ynopyranoside 
• 103597-25-7 methyl 6,7-di-O-acetyl-2,3,4-tri-O-benzyl-L-glycero-α-D-gluco-heptopyranoside 
• 103597-24-6 methyl 2,3,4-tri-O-benzyl-L-glycero-α-D-gluco-heptopyranoside 
• 161147-39-3 Methyl 6-azido-2,3,4-tri-O-benzyl-6-deoxy-L-glycero-α-D-gluco-heptopyranosiduronic acid benzyl ester 
• 161147-38-2 Methyl 6-azido-2,3,4-tri-O-benzyl-6-deoxy-D-glycero-α-D-gluco-heptopyranosiduronic acid benzyl ester 
• 161147-43-9 Methyl 6-(N-acetylamino)-2,3,4-tri-O-benzyl-6-deoxy-L-glycero-α-D-gluco-heptopyranosiduronic acid benzyl ester 
• 161147-42-8 Methyl 6-(N-acetylamino)-2,3,4-tri-O-benzyl-6-deoxy-D-glycero-α-D-gluco-heptopyranosiduronic acid benzyl ester 
• 1053744-41-4 (R)-Amino-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-acetic acid benzyl ester 
• 1053723-75-3 (S)-Amino-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-acetic acid benzyl ester 
• 1053264-49-5 (R)-Azido-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-acetic acid 
• 1054622-71-7 (R)-Acetylamino-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-acetic acid 
• 1055033-90-3 (S)-Acetylamino-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-acetic acid 

Relevant academic research and scientific papers

Chain-extension of carbohydrates. 5. Synthesis of the C-glycosyl amino acid moiety of miharamycins involving stereocontrolled ethynylation of methyl 2,3,4-tri-O-benzyl-α-D-gluco-hexodialdo-1,5-pyranoside

A multistep synthesis of the C-glycosyl amino acid moiety of miharamycins from methyl 2,3,4-tri-O-benzyl-α-D-gluco-hexodialdo-1,5-pyranoside (1) is described. The ethynyl group was employed as a synthetic equivalent of the carboxylic acid function. In the