1036-14-2

Basic information

• Product Name: 1-(((4-methoxyphenyl)imino)methyl)-2-naphthol
• Synonyms: 1-{[(4-methoxyphenyl)amino]methylidene}naphthalen-2(1H)-one
• CAS NO: 1036-14-2
• Molecular Formula: C₁₈H₁₅NO₂
• Molecular Weight: 277.3172
• Mol File: 1036-14-2.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 490.1°C at 760 mmHg
• Flash Point: 250.2°C
• Density: 1.292g/cm³
• Vapor Pressure: 9.41E-10mmHg at 25°C
• Refractive Index: 1.721
• CAS DataBase Reference: 1-(((4-methoxyphenyl)imino)methyl)-2-naphthol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(((4-methoxyphenyl)imino)methyl)-2-naphthol(1036-14-2)
• EPA Substance Registry System: 1-(((4-methoxyphenyl)imino)methyl)-2-naphthol(1036-14-2)

Safety Data

• Hazardous Substances Data: 1036-14-2(Hazardous Substances Data)

Usage

General Description

The chemical compound 1-(((4-methoxyphenyl)imino)methyl)-2-naphthol is a complex organic compound with a molecular formula of C19H15NO2. It is composed of a naphthol ring with a methoxyphenyl group attached to it, along with an imino group connected to the methoxyphenyl group. 1-(((4-methoxyphenyl)imino)methyl)-2-naphthol is commonly used as a dye and pigment in various industrial and research applications due to its colorful and light-absorbing properties. It may also have potential uses in pharmaceutical and medicinal fields, although further research and testing would be necessary to determine its specific applications in these areas.

Upstream product

• 104-94-9 4-methoxy-aniline 
• 122-51-0 orthoformic acid triethyl ester 
• 135-19-3 β-naphthol 
• 708-06-5 2-hydroxynaphthalene-1-carbaldehyde 
• 731-90-8 N-(2-hydroxy-1-naphthalidene)aniline 
• 6638-95-5 1-(phenylaminomethyl)naphthalen-2-ol 
• 106-49-0 p-toluidine 

Downstream Products

• 64678-90-6 N-(4-Methoxyphenyl)-3-oxo-3H-naphtho<2,1-b>pyran-2-carboxamid 
• 97095-02-8 3-Oxo-3H-naphtho<2,1-b>pyran-2-carbonsaeure-(2,4,6-trichlorphenylester) 
• 139640-65-6 (1,2-Dihydro-naphtho[2,1-b]furan-1-yl)-(4-methoxy-phenyl)-amine 
• 97095-06-2 1,4,4a,12c-Tetrahydro-N-(4-methoxyphenyl)-2,3-dimethyl-5-oxo-5H-6-oxabenzophenanthren-4a-carboxamid 
• 97095-07-3 8a,9,10,11,12,13,14,14a-Octahydro-N-(4-methoxyphenyl)-8-oxo-8H-7-oxanaphth<1,2-a>anthracen-8a-carboxamid 
• 904286-88-0 RuCl₂(AsPh₃)2(NMOA) 
• 105236-77-9 SnCl₂(C₆H₄C₄H₂(OH)CHNC₆H₄OCH₃)2 
• 105236-78-0 SnBr₂(C₆H₄C₄H₂(OH)CHNC₆H₄OCH₃)2 
• 105236-76-8 Sn(NCS)2(C₆H₄C₄H₂(OH)CHNC₆H₄OCH₃)2 

Relevant articles and documents

Synthesis of a series of new platinum organometallic complexes derived from bidentate Schiff-base ligands and their catalytic activity in the hydrosilylation and dehydrosilylation of styrene

The synthesis and properties of a novel class of platinum complexes containing Schiff bases as O,N-bidentate ligands is described as are the solution and solid state properties of the uncomplexed ligands. The platinum complexes were prepared from [PtBr2(COD)] (COD = 1,5-cyclooctadiene) and N-(2-hydroxy-1-naphthalidene)aniline derivatives in the presence of base (NaOBut). Instead of a substitution reaction to afford cationic species, the addition of the Schiff base ligands results in both the formal loss of two equivalents of bromide and addition of hydroxide to the COD ligand of the complexes. It is proposed that this reaction proceeds through a cationic platinum complex [Pt(N-O)(COD)]Br which then undergoes addition of water and loss of HBr. An example of a dinuclear platinum complex in which two cyclo-octene ligands are bridged by an ether linkage is also reported. The platinum complexes were evaluated as catalysts for the hydrogenative and dehydrogenative silylation of styrene, the resulting behaviour is substituent, time and temperature dependent.

Synthesis, spectroscopic characterization, catalytic and antibacterial studies of ruthenium(III) Schiff base complexes

The bidentate Schiff base ligands (HLn) have been synthesized by condensation of 2-hydroxy-l-naphthaldehyde with aniline and its p-substituted derivatives in ethanol. Ruthenium(III) complexes of the type [Ru(Ln)2(H2O)2]Cl have been synthesized by the reaction of RuCl3·nH2O with the Schiff base ligands (in a molar ratio 1:2) in ethanol. The ligands and their Ru(III) complexes have been characterized by elemental analysis, magnetic susceptibility, spectroscopic (FTIR, UV-vis, 1H NMR and X-ray diffraction) and thermal analysis techniques. All the ruthenium(III) complexes are found to be stable, paramagnetic, low spin and octahedrally coordinated by the ligands through the nitrogen atom of the azomethine (-CN-) group and the oxygen atom of the deprotonated phenolic group. The molecular and electronic structures of the investigated ligands (HLn) were also studied using quantum chemical calculations. The complexes (1, 3 and 5) exhibited a catalytic activity for the oxidation of benzoin to benzil with moderate to high yield in the presence of sodium periodate as co-oxidant. The antibacterial activities of the ligands (HLn) and their Ru(III) complexes towards Gram positive and Gram negative bacteria have been investigated.

N,O-coordinated bivalent nickel complex with binaphthol structure and preparation method thereof

The invention provides N,O-coordinated bivalent nickel complex with binaphthol structure, having a structural formula shown in the description; the invention also provides a preparation method of the N,O-coordinated bivalent nickel complex with binaphthol