1036028-81-5Relevant articles and documents
Amine-assisted C-Cl bond activation of aryl chlorides by a (phebox)Rh-chloro complex
Ito, Jun-Ichi,Miyakawa, Takeshi,Nishiyama, Hisao
, p. 3312 - 3315 (2008)
Oxidative addition of chlorobenzene and p-chlorotoluene by (Phebox)RhCl2(H2O) (1) in the presence of diisopropylamine was examined and was shown to produce the corresponding aryl complexes (Phebox)RhCl(Ar)(H2O) in high yields via C-Cl bond cleavage. Reaction of 1 with chloropyridine in the presence of diisopropylamine provided a pyridinium rhodate complex.