103603-53-8

Basic information

• Product Name: N-(4-methylphenylthiomethyl)benzamide
• Synonyms: N-(4-methylphenylthiomethyl)benzamide
• CAS NO: 103603-53-8
• Molecular Weight: 257.356
• Mol File: 103603-53-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-(4-methylphenylthiomethyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-methylphenylthiomethyl)benzamide(103603-53-8)
• EPA Substance Registry System: N-(4-methylphenylthiomethyl)benzamide(103603-53-8)

Safety Data

• Hazardous Substances Data: 103603-53-8(Hazardous Substances Data)

Upstream product

• 1309964-21-3 C₁₆H₁₅NO₂S 
• 934-72-5 Methyl p-tolyl sulfoxide 
• 100-47-0 benzonitrile 
• 6282-02-6 N-(hydroxymethyl)benzamide 
• 106-45-6 para-thiocresol 

Downstream Products

• 100-47-0 benzonitrile 
• 124778-69-4 2-phenyl-6-methyl-4H-1,3-benzothiazine 
• 106-45-6 para-thiocresol 
• 150536-47-3 2-(4-chlorophenyl)-6-methyl-4H-1,3-benzothiazine 

Relevant articles and documents

Nickel-Catalyzed Selective Decarbonylation of α-Amino Acid Thioester: Aminomethylation of Mercaptans

The nickel-catalyzed aminomethylation of mercaptans has been disclosed that offers efficient and expedient access to synthesize α-aminosulfides. The intramolecular fragment coupling shows excellent chemoselectivity. This transformation shows good functional-group compatibility, tolerates a wide range of electron-withdrawing, electron-neutral, and electron-donating substituents in this process, and can serve as a powerful synthetic tool for the synthesis of α-aminosulfides at a gram scale. Thus, the newly developed methodology enables a facile route for C-S bond formation in a straightforward fashion.

REACTION OF SULFOXIDES WITH NITRILES IN PRESENCE OF TRIFLUOROACETIC ANHYDRIDE AND TRIFLUOROACETIC ACID: A CASE OF RITTER REACTION OF PUMMERER INTERMEDIATE

Reaction of various sulfoxides 9, with nitriles 10 in presence of trifluoroacetic anhydride and trifluoroacetic acid gave the corresponding amides 11 via a Ritter reaction on Pummerer intermediate derived from the sulfoxides.