103618-29-7Relevant articles and documents
Nickel catalyzed Grob fragmentation: ω-dienyl aldehydes synthesis
Mori, Masahiko,Kimura, Masanari,Takahashi, Yushi,Tamaru, Yoshinao
, p. 4303 - 4305 (2007/10/03)
With a proper choice of phosphane ligands, a Ni(cod)2-phosphane catalyst promotes decarboxylative ring-opening reaction of a wide structural variety of cyclic carbonates 1 to give ω-dienyl aldehydes 2 in good yields. The Royal Society of Chemis
Synthesis of (+/-)-Desmarestene and (+/-)-Viridiene, the Two Sperm Releasing and Attracting Pheromones from the Brown Algae Desmarestia aculeata and Desmarestia viridis
Boland, Wilhelm,Jakoby, Karin,Jaenicke, Lothar
, p. 2355 - 2362 (2007/10/02)
Desmarestene 1 6-(1Z,3-butadienyl)-1,4-cycloheptadiene) and viridiene 3 cis-3-(1Z,3-butadienyl)-4-vinylcyclopentene) are chemical messengers for male gametes of the brown algae Desmarestia aculeata and Desmarestia viridis.Total syntheses of 1, 3 and their stereoisomers 1a, 3a-c are reported.Gas-chromatographic comparison of synthetic 1 and 3 with the corresponding natural products has established their structural identity.