103618-46-8Relevant articles and documents
Enantioselective Reduction of Vicinally Substituted Monocyclic Aldehydes with Horse Liver Alcohol Dehydrogenase; A New Approach to Chiral Alcohols and Aldehydes
Boland, Wilhelm,Niedermeyer, Uwe
, p. 28 - 32 (1987)
Optically active, vicinally substituted monocyclic aldehydes and alcohols can be conveniently prepared by enantioselective reduction of racemic aldehydes by means of horse liver alcohol dehydrogenase (HLADH) under kinetically controlled conditions.
The first total synthesis of (+)-mucosin
Henderson, Alan R.,Stec, Jozef,Owen, David R.,Whitby, Richard J.
supporting information; experimental part, p. 3409 - 3411 (2012/05/20)
The first total synthesis of (+)-mucosin has been completed allowing assignment of the absolute stereochemistry of the natural product. A zirconium induced co-cyclisation was utilised to install the correct stereochemistry of the four contiguous stereocentres around the unusual bicyclo[4.3.0]nonene core.
Studies in iridoid synthesis. Chemoselective transformations of cis-1,2,4,6-tetrahydrophthalic anhydride
Stevens, Anne T.,Bull, James R.,Chibale, Kelly
supporting information; experimental part, p. 586 - 595 (2008/10/09)
In the course of synthetic studies towards the development of diastereoselective routes to secoiridoid aglycones, cis-1,2,4,6- tetrahydrophthalic anhydride was transformed into the corresponding lactone cis-3a,4,7,7a-tetrahydro-3H-isobenzofuran-1-one, whi
Chemoselectivity and unusual internal acetal formation in the synthesis of a glycosidation precursor
Stevens, Anne T.,Bull, James R.,Chibale, Kelly
, p. 3175 - 3179 (2008/09/19)
Chemoselective deprotection of a tert-butyldimethyl (TBS) silyl ether group in the presence of an acetal moiety within an advanced iridoid precursor using scandium trifluoromethane-sulfonate at 25°C unexpectedly leads to internal acetal formation in high
217. Enantioselective Syntheses and Absolute Configurations of Viridiene and Aucantene, Two Constituents of Algae Pheromone Bouquets
Boland, Wilhelm,Niedermeyer, Uwe,Jaenicke, Lothar,Goerisch, Helmut
, p. 2062 - 2073 (2007/10/02)
Viridiene ((+)-6; (+)-(3R,4S)-3-((1Z)-1,3-butadienyl)-4-vinylcyclopentene) and aucantene ((+)-18; (+)-(4R,5R)-4-((1E)-1-propenyl)-5-vinylcyclohexene) are constituents of the pheromone bouquets of several brown algae species.Key synthons to the title compo