103620-07-1

Basic information

• Product Name: 2-Propenenitrile, 3-[2-(2,2-dimethylcyclopropyl)-3,3-dimethyl-1-cyclopropen-1-yl]-, (E)-
• CAS NO: 103620-07-1
• Molecular Formula: C13H17N
• Molecular Weight: 189.301
• Mol File: 103620-07-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Propenenitrile, 3-[2-(2,2-dimethylcyclopropyl)-3,3-dimethyl-1-cyclopropen-1-yl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenenitrile, 3-[2-(2,2-dimethylcyclopropyl)-3,3-dimethyl-1-cyclopropen-1-yl]-, (E)-(103620-07-1)
• EPA Substance Registry System: 2-Propenenitrile, 3-[2-(2,2-dimethylcyclopropyl)-3,3-dimethyl-1-cyclopropen-1-yl]-, (E)-(103620-07-1)

Safety Data

• Hazardous Substances Data: 103620-07-1(Hazardous Substances Data)

Upstream product

• 107-13-1 acrylonitrile 
• 3907-06-0 3,3-Dimethylcyclopropen 

Relevant articles and documents

Reactions of Cyclopropenes, VII. Nickel(0)-catalyzed Cotrimerisation of 3,3-Dimethylcyclopropene with Methyl Acrylate

The cotrimerisation of 3,3-dimethylcyclopropene (1) with methyl acrylate is catalyzed by phosphane- or phosphite-Ni(0) compounds under mild conditions (40 - 50 deg C).Depending on the nature of the phosphane or phosphite 1 and methyl acrylate cotrimerise mainly in the ratio 2 : 1 or 1 : 2 to give cis/trans-5 or cis/trans-6 and cyclic cis/trans-7. trans-5 and trans-6 are thermally more labile than the corresponding cis compounds.Heating to 200 deg C for two hours induces their complete rearrangement to 12 and 13 or 14 via 1,5-homodienylhydrogen shift.