103624-41-5

Upstream product

• 52884-09-0 (2SR,3RS)-3-methyl-2-phenylpent-4-yn-2-ol 
• 103624-26-6 (4S,5R)-4,5-Dimethyl-5-phenyl-tetrahydro-furan-2-ol 

Downstream Products

• 131259-23-9 (2S,3R,4R,5S)-4,5-Dibromo-2,3-dimethyl-2-phenyl-tetrahydro-furan 
• 131259-23-9 (2S,3R,4R,5R)-4,5-Dibromo-2,3-dimethyl-2-phenyl-tetrahydro-furan 
• 131259-23-9 (2S,3R,4S,5S)-4,5-Dibromo-2,3-dimethyl-2-phenyl-tetrahydro-furan 
• 131259-23-9 (2S,3R,4S,5R)-4,5-Dibromo-2,3-dimethyl-2-phenyl-tetrahydro-furan 
• 131259-23-9 (2S,3S,4R,5S)-4,5-Dibromo-2,3-dimethyl-2-phenyl-tetrahydro-furan 
• 131259-23-9 (2S,3S,4R,5R)-4,5-Dibromo-2,3-dimethyl-2-phenyl-tetrahydro-furan 
• 131259-23-9 (2S,3S,4S,5R)-4,5-Dibromo-2,3-dimethyl-2-phenyl-tetrahydro-furan 
• 112359-42-9 4α,5α-dideuterio 2α,3α-methyl 2β-phenyl tetrahydrofuran 
• 112359-42-9 4β,5β-dideuterio 2α,3α-methyl 2β-phenyl tetrahydrofuran 
• 112359-42-9 4α,5α-dideuterio 2α,3β-dimethyl 2β-phenyl tetrahydrofuran 

Relevant academic research and scientific papers

SYNTHESE DE COMPOSES DIHYDRO-2,3 FURANNIQUES PAR HYDROBORATION D'ALCOOLS β-ACETYLENIQUES

Hydroboration of β acetylenic alcohols followed by NaOH/H2O2 oxidation leads to hemiacetals of γ aldols which are easily dehydrated to 2,3-dihydrofuran compounds.The reaction gives good yields with hindered alcohols and its stereochemistry may be controlled during the organometallic synthesis of the starting alcohol.