103659-57-0Relevant articles and documents
Titanocene(II)-promoted carbonyl alienation utilizing 1, 1-dichloroalk-1-enes
Shono, Tomohiro,Ito, Kenji,Tsubouchi, Akira,Takeda, Takeshi
, p. 2914 - 2916 (2007/10/03)
Treatment of 1,1-dichloroalk-1-enes with Cp2Ti[P(OEt) 3]2 produced organotitanium species, which afford allenes on treatment with aldehydes and ketones The Royal Society of Chemistry 2005.
Chromium(II) Reduction of Trichloromethyl Carbinols and their Corresponding Ethers: One-step Synthesis of Z-Vinyl Chlorides
Wolf, Reinhard,Steckhan, Eberhard
, p. 733 - 740 (2007/10/02)
Secondary trichloromethyl carbinols and their corresponding ethers can be reduced by chemically or electrochemically generated chromium(II) chloride to form Z-monochlorovinyl compounds in one step.In the presence of a carboxy function in the α-position an E-double bond is formed.Tertiary cabinols favour the formation of dichlorovinyl compounds and rearranged carbonyl compounds.Product ratios can be altered drastically by a change in the reaction conditions; this sheds light on the reaction mechanism.