1036648-27-7

Basic information

• Product Name: adamantan-1-yl 4-methylbenzoate
• Synonyms: adamantan-1-yl 4-methylbenzoate
• CAS NO: 1036648-27-7
• Molecular Weight: 270.371
• Mol File: 1036648-27-7.mol

Chemical Properties

• CAS DataBase Reference: adamantan-1-yl 4-methylbenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: adamantan-1-yl 4-methylbenzoate(1036648-27-7)
• EPA Substance Registry System: adamantan-1-yl 4-methylbenzoate(1036648-27-7)

Safety Data

• Hazardous Substances Data: 1036648-27-7(Hazardous Substances Data)

Upstream product

• 768-95-6 1-adamanthanol 
• 99-94-5 p-Toluic acid 
• 281-23-2 adamantane 
• 874-60-2 4-methyl-benzoyl chloride 

Downstream Products

• 281-23-2 adamantane 
• 768-95-6 1-adamanthanol 

Relevant articles and documents

Construction of Esters through Sulfuryl Fluoride (SO 2 F 2) Mediated Dehydrative Coupling of Carboxylic Acids with Alcohols at Room Temperature

A facile method for the construction of esters through dehydrative coupling of carboxylic acids with alcohols is developed. The reactions are mediated by sulfuryl fluoride (SO 2 F 2) at room temperature and proceed with high efficiency. The method has several advantages including broad substrate scope, mild conditions, excellent functional group compatibility and affords high yields, even on gram scale.

Copper-catalyzed oxidative esterification of unactivated C(sp3)-H bonds with carboxylic acids via cross dehydrogenative coupling

An effective copper-catalyzed esterification of unactivated (non-benzylic and allylic) C(sp3)-H bonds of hydrocarbons with Selectfluor as an oxidant has been developed. This reaction could provide a direct, new and useful strategy for the synthesis of esters and alkyl alcohols by ester hydrolysis.

Organic electrosynthesis using toluates as simple and versatile radical precursors

The electrolysis of toluate esters leads smoothly to the formation of the radical of the alkyl fragment. This property has been used to develop a new electrochemical deoxygenation reaction. The Royal Society of Chemistry.

Chemoselective chemical and electrochemical deprotections of aromatic esters

Alcohols can be easily and chemoselectively deprotected from the corresponding aromatic esters by using either SmI2/HMPA or by electrolysis In the presence of a proton source.

Toluates: unexpectedly versatile reagents

The mechanism of the monoelectronic reduction of aromatic esters has been investigated. The unexpected synthetic utility of the toluate moiety in the deoxygenation of alcohols and the allylation of ketones is also reported. Finally, the use of aromatic esters as robust, though easily removable, protecting groups is depicted.

Using toluates as simple and versatile radical precursors

(Chemical Equation Presented) The viability of the toluate moiety as a radical precursor has been examined by studying deoxygenation and cyclization reactions.