103681-95-4Relevant articles and documents
The Directed ortho Metalation (D o M)-Cross-Coupling Connection: Synthesis of Polyfunctional Biaryls
Quesnelle, Claude A.,Snieckus, Victor
, p. 4413 - 4428 (2018)
A comparative evaluation of the combined directed ortho metalation (D o M)-Suzuki-Miyaura and D o M-Negishi cross-coupling reactions with aryl triflates for the synthesis of substituted biaryls is described. Both ortho -zinc and ortho -boron aryl directed
SYNTHETIC CONNECTIONS TO THE AROMATIC DIRECTED METALATION REACTION. UNSYMMETRICAL BIARYLS BY PALLADIUM-CATALYZED CROSS COUPLING OF DIRECTED METALATION-DERIVED ARYLBORONIC ACIDS WITH ARYL HALIDES
Sharp, M.J.,Snieckus, V.
, p. 5997 - 6000 (2007/10/02)
The arylboronic acids 2 and 4 derived by directed ortho metalation of benzamides and carbamates, undergo an efficient palladium-catalyzed cross coupling reaction with a variety of aryl halides to yield unsymmetrical biaryls and heterobiaryls (Table).