103681-95-4

Basic information

• Product Name: Benzamide, N,N-bis(1-methylethyl)-2-(3-pyridinyl)-
• CAS NO: 103681-95-4
• Molecular Formula: C18H22N2O
• Molecular Weight: 282.385
• Mol File: 103681-95-4.mol

Chemical Properties

• CAS DataBase Reference: Benzamide, N,N-bis(1-methylethyl)-2-(3-pyridinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, N,N-bis(1-methylethyl)-2-(3-pyridinyl)-(103681-95-4)
• EPA Substance Registry System: Benzamide, N,N-bis(1-methylethyl)-2-(3-pyridinyl)-(103681-95-4)

Safety Data

• Hazardous Substances Data: 103681-95-4(Hazardous Substances Data)

Upstream product

• 626-55-1 3-Bromopyridine 
• 107658-27-5 pyridin-3-yl trifluoromethanesulfonate 
• 20383-28-2 N,N-diisopropyl benzamide 
• 103681-98-7 2-diisopropylaminocarbonylphenylboronic acid 

Downstream Products

• 18631-22-6 5H-indeno[1,2-c]pyridin-5-one 

Relevant articles and documents

The Directed ortho Metalation (D o M)-Cross-Coupling Connection: Synthesis of Polyfunctional Biaryls

A comparative evaluation of the combined directed ortho metalation (D o M)-Suzuki-Miyaura and D o M-Negishi cross-coupling reactions with aryl triflates for the synthesis of substituted biaryls is described. Both ortho -zinc and ortho -boron aryl directed

SYNTHETIC CONNECTIONS TO THE AROMATIC DIRECTED METALATION REACTION. UNSYMMETRICAL BIARYLS BY PALLADIUM-CATALYZED CROSS COUPLING OF DIRECTED METALATION-DERIVED ARYLBORONIC ACIDS WITH ARYL HALIDES

The arylboronic acids 2 and 4 derived by directed ortho metalation of benzamides and carbamates, undergo an efficient palladium-catalyzed cross coupling reaction with a variety of aryl halides to yield unsymmetrical biaryls and heterobiaryls (Table).