103682-02-6

Basic information

• Product Name: 3-(phenylseleno)-1-cycloocten-4-ol
• Synonyms: 3-(phenylseleno)-1-cycloocten-4-ol
• CAS NO: 103682-02-6
• Molecular Weight: 281.256
• Mol File: 103682-02-6.mol

Chemical Properties

• CAS DataBase Reference: 3-(phenylseleno)-1-cycloocten-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(phenylseleno)-1-cycloocten-4-ol(103682-02-6)
• EPA Substance Registry System: 3-(phenylseleno)-1-cycloocten-4-ol(103682-02-6)

Safety Data

• Hazardous Substances Data: 103682-02-6(Hazardous Substances Data)

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 3806-59-5 1,3-cyclooctadiene 
• 6690-12-6 (Z)-9-oxabicyclo[6.1.0]non-2-ene 
• 1666-13-3 diphenyl diselenide 

Downstream Products

• 148705-60-6 (Z)-4-[(E)-1-Methyl-3-(2,6,6-trimethyl-cyclohex-1-enyl)-prop-2-en-(E)-ylidene]-cyclooct-2-enone 
• 148705-59-3 (Z)-4-[(E)-1-Methyl-3-(2,6,6-trimethyl-cyclohex-1-enyl)-prop-2-en-(E)-ylidene]-cyclooct-2-enol 

Relevant articles and documents

Synthesis of Retinals with Eight- and Nine-Membered Rings in the Side Chain. Models for Rhodopsin Photobleaching Intermediates

The triggering process of rhodopsin activation leading to visual transduction has remained a key problem in the chemistry of vision.In order to provide probes to explore this process, retinal analogs ret8 3 and ret9 4, with the 11-ene cis-locked by 8- and

PHENYLSELENENYL CHLORIDE IN ACETONITRILE-WATER; A HIGHLY CONVENIENT REAGENT FOR HYDROXYSELENATION OF OLEFINS AND PREPARATION OF CYCLIC ETHERS FROM DIENES

The reaction of phenylselenenyl chloride with olefins in aqueous acetonitrile affords β-hydroxyalkyl phenyl selenides in excellent yields, providing the most convenient method for hydroxyselenation of olefins so far reported.When the reaction was applied to conjugated dienes, monohydroxyselenated products were obtained in good to excellent yields.From non-conjugated dienes, on the other hand, cyclic ethers containing two phenylseleno groups were produced in good to excellent yields, the first step of this reaction being the hydroxyselenation of one double bond.