1036999-80-0

Basic information

• Product Name: [Pd2(μ-SMes)2(η3-metallyl)2]
• CAS NO: 1036999-80-0
• Molecular Weight: 625.544
• Mol File: 1036999-80-0.mol

Chemical Properties

• CAS DataBase Reference: [Pd2(μ-SMes)2(η3-metallyl)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Pd2(μ-SMes)2(η3-metallyl)2](1036999-80-0)
• EPA Substance Registry System: [Pd2(μ-SMes)2(η3-metallyl)2](1036999-80-0)

Safety Data

• Hazardous Substances Data: 1036999-80-0(Hazardous Substances Data)

Downstream Products

• 1036999-82-2 [Pd3(μ-SMes)4(η3-metallyl)2] 

Relevant articles and documents

Synthesis and characterization of chalcogenolato-bridged allyl palladium complexes: Versatile precursors for palladium chalcogenides

The complexes [Pd(μ-ER)(η3-allyl)]2 (ER = EMes; E = S, Se; allyl = C3H5, C4H7) have been isolated by the reaction of [Pb(ER)2]n with [Pd2(μ-Cl)2(η3-allyl)2]. Similar reactions with [Pb(SeCH2CH2NMe2) 2]n resulted in the formation of a trinuclear complex [Pd3Cl2(κ2-Se,N-SeCH2CH 2NMe2)(η3-allyl)3]. Treatment of [Pd(μ-SR)(η3-C4H7)]2 with [Pd(SMes)2]n in 1:1 ratio yielded [Pd3(μ- SMes)4(η3-C4H7)2]. These complexes were characterized by elemental analyses and mass, UV-vis, and NMR spectroscopy. The structures of [Pd2(μ-EMes)2(η 3-C4H7)2] (E = S, Se) were established by single-crystal X-ray diffraction analysis, which revealed a syn configuration. Two new structural motifs for [Pd3Cl 2(κ2-Se,N-SeCH2CH2NMe 2)(η3-C3H5)3] and [Pd3(μ-SMes)4(η3-C4H 7)2] have also been identified. Pyrolysis of [Pd(μ-ER)(η3-C4H7)]2 yielded palladium chalcogenides, which were characterized by powder XRD and EDAX.