1037195-15-5Relevant articles and documents
Specific insertion reactions of a germylene, stannylene and plumbylene into the unique P-P bond of the hexaphospha-pentaprismane cage, P6C 4tBu4: Crystal and molecular structures of P6C4tBu4ER2 (E = Ge, Sn, R = N(SiMe3)2; E = Pb, R = (C6H 3 ...
Al-Ktaifani, Mahmoud M.,Hitchcock, Peter B.,Lappert, Michael F.,Nixon, John F.,Uiterweerd, Philip
, p. 2825 - 2831 (2008)
Full title: Specific insertion reactions of a germylene, stannylene and plumbylene into the unique P-P bond of the hexaphospha-pentaprismane cage, P6C 4tBu4: Crystal and molecular structures of P6C4tBu4ER2 (E = Ge, Sn, R = N(SiMe3)2; E = Pb, R = (C6H 3(NMe2)2 -2,6). Treatment of the cage compound P6C4 tBu4 with M{N(SiMe3)2}2 (M = Ge or Sn) or Pb(C6H3(NMe2) 2-2,6) at room temperature results in their specific insertion into the P-P bond connecting the two 5-membered P3C2 tBu2 rings. The products were fully characterised by multinuclear NMR spectroscopy and single crystal X-ray diffraction studies. The Royal Society of Chemistry.