1037204-47-9Relevant articles and documents
A cross-metathesis approach to the stereocontrolled synthesis of the AB ring segment of ciguatoxin
Kadota, Isao,Abe, Takashi,Uni, Miyuki,Takamura, Hiroyoshi,Yamamoto, Yoshinori
, p. 3643 - 3647 (2008/09/20)
Synthesis of the AB ring segments of ciguatoxin is described. The present synthesis includes a Lewis acid mediated cyclization of allylstannane with aldehyde, cross-metathesis reaction introducing the side chain, and Grieco-Nishizawa dehydration on the A ring.