1037290-38-2

Basic information

• Product Name: C₆₂H₉₆N₂O₁₉
• CAS NO: 1037290-38-2
• Molecular Weight: 1173.45
• Mol File: 1037290-38-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₆₂H₉₆N₂O₁₉(CAS DataBase Reference)
• NIST Chemistry Reference: C₆₂H₉₆N₂O₁₉(1037290-38-2)
• EPA Substance Registry System: C₆₂H₉₆N₂O₁₉(1037290-38-2)

Safety Data

• Hazardous Substances Data: 1037290-38-2(Hazardous Substances Data)

Upstream product

• 1945-85-3 2-methyl-5-pyridylacetylene 
• 1037290-36-0 C₄₆H₈₄I₂O₁₉ 

Relevant articles and documents

Folding of coordination polymers into double-stranded helical organization

Self-assembling coordination polymers based on PdII and Cu II metal ions were prepared from complexation of a bent-shaped bispyridine ligand and a corresponding transition metal. These coordination polymers were observed to self-assemble into supramolecular structures that differ significantly depending on the coordination geometry of the metal center. The polymer based on PdII self-assembles into a layer structure formed by bridging bispyri dine ligands connected in a trans-position of the square-planar coordination geometry of metal center. In contrast, the polymer based on CuII adopts a double-helical conformation with regular grooves, driven by interstranded, copper-chloride dimeric interaction. The double-stranded helical organization is further confirmed by structure optimization from density functional theory with aromatic framework, showing that the optimized double-helical structure is energetically favorable and consistent with the experimental results. These results demonstrate that weak metal-ligand bridging interactions can provide a useful strategy to construct stable double-stranded helical nanotubes.