1037300-84-7

Basic information

• Product Name: C₁₅₅H₁₈₃N₉O₂₇S₁₂
• Synonyms: C₁₅₅H₁₈₃N₉O₂₇S₁₂
• CAS NO: 1037300-84-7
• Molecular Weight: 2988.99
• Mol File: 1037300-84-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₅₅H₁₈₃N₉O₂₇S₁₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅₅H₁₈₃N₉O₂₇S₁₂(1037300-84-7)
• EPA Substance Registry System: C₁₅₅H₁₈₃N₉O₂₇S₁₂(1037300-84-7)

Safety Data

• Hazardous Substances Data: 1037300-84-7(Hazardous Substances Data)

Upstream product

• 1033921-02-6 1,3-diisopropyl-2-(prop-2-yn-1-yloxy)benzene 
• 1037300-89-2 C₁₁₀H₁₂₃N₉O₂₄S₁₂ 

Relevant articles and documents

Tetrathiafulvalene radical cation dimerization in a bistable tripodal [4]rotaxane

The template-directed synthesis of a bistable tripodal [4]rotaxane, which has cyclobis(paraquat-p-phenylene) (CBPQT4+) as the π-electron-de-ficient rings, and tetrathiafulvalene (TTF) and 1,5-dioxynaphthalene units as the pairs of π-electron-rich recognition sites located on all three legs of the tripodal dumbbell, is described. The chemical and electrochemical oxidation of the [4]rotaxane and its tripo dal dumbbell have allowed us to unravel an unprecedented TTF+ radical cation dimerization. In fact, two types of TTF dimers, namely, the radical cation dimer [TTF+]2 and the mixed-valence one [(TTF) 2]+, have been ob served at room temperature for the tripodal dumbbell, whereas, in the case of the [4]rotaxane, only the radical cation dimer [TTF+]2 is formed. This anomaly can be explained if it is accepted that most of the neutral TTF units in the [4]rotaxane are encircled by CBPQT4+ rings, which renders the formation of the mixed-valence dimer [(TTF)2]+ highly unfavorable.