1037405-07-4Relevant academic research and scientific papers
Electrocatalytic reduction of aryldichlorophosphines with the (2,2′-bipyridine)nickel complexes
Yakhvarov,Hey-Hawkins,Kagirov,Budnikova,Ganushevich,Sinyashin
, p. 935 - 942 (2007)
The reduction of aryldichlorophosphines in organic solvents was studied by cyclic voltammetry, preparative electrolysis, and chemical reduction. The reaction of the electrochemically generated (2,2′-bipyridine)nickel(0) complexes with aryldichlorophosphines PhPCl2 and tippPCl2 (tipp is 2,4,6-triisopropylphenyl) proceeds through the formation of highly reactive organophosphorus intermediates, whose reactions with diphenylacetylene and hex-1-ene afford phosphirene and phosphirane heterocycles, respectively.
