103754-42-3

Basic information

• Product Name: 2-Propenoic acid, 3-(2,4-dichlorophenyl)-2-Methyl-
• Synonyms: 2-Propenoic acid, 3-(2,4-dichlorophenyl)-2-Methyl-;3-(2,4-Dichlorophenyl)-2-methyl-2-propenoic acid
• CAS NO: 103754-42-3
• Molecular Formula: C₁₀H₈Cl₂O₂
• Molecular Weight: 231.07532
• Mol File: 103754-42-3.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Propenoic acid, 3-(2,4-dichlorophenyl)-2-Methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-(2,4-dichlorophenyl)-2-Methyl-(103754-42-3)
• EPA Substance Registry System: 2-Propenoic acid, 3-(2,4-dichlorophenyl)-2-Methyl-(103754-42-3)

Safety Data

• Hazardous Substances Data: 103754-42-3(Hazardous Substances Data)

Usage

General Description

2-Propenoic acid, 3-(2,4-dichlorophenyl)-2-methyl- is a chemical compound with the molecular formula C11H8Cl2O2. It is also known as 2,4-dichlorophenyl methyl 3-acryloyloxypropionate and is used in the production of adhesives, coatings, and sealants. 2-Propenoic acid, 3-(2,4-dichlorophenyl)-2-methyl- is classified as an acrylate and is commonly used in the manufacture of polymers and resins. It is a colorless to pale yellow liquid with a characteristic odor and is considered to be a skin and eye irritant. It is important to handle this chemical with care and use appropriate safety measures when working with it.

Upstream product

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• 1367876-27-4 [(Z)-3-(2,4-dichlorophenyl)-2-methoxycarbonyl-2-propenyl]triphenylphosphonium bromide 
• 364633-51-2 (E)-3-(2,4-Dichloro-phenyl)-2-methyl-acrylic acid methyl ester 
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Relevant articles and documents

Microwave-assisted synthesis of the (E)-α-methylalkenoate framework from multifunctionalized allylic phosphonium salts

A convenient and general microwave-assisted method for the synthesis of stereochemically defined α-methylalkenoic acids and esters from allylic phosphonium salts in a basic aqueous medium is described. A selective preparation of acids or esters was dependent on the base (NaOH or NaHCO 3) employed in the reaction and could be achieved with good to excellent yields under mild conditions in the absence of hydrides and reducing agents.

A facile one-pot stereoselective synthesis of trisubstituted (E)-2-methylalk-2-enoic acids from unactivated Baylis-Hillman adducts and a simple access to some important insect pheromones

An efficient one-pot stereoselective synthesis of trisubstituted (E)-2-methylalk-2-enoic acids has been accomplished by treatment of unactivated Baylis-Hillman adducts, 3-hydroxy-2-methylenealkanoates, with Al-NiCl2·6H2O in methanol at room temperature followed by hydrolysis. The method has been applied to the synthesis of three important insect pheromones, (4S,2E)-2,4-dimethyl-2-hexenoic acid, (+)-(S)-manicone and (+)-(S)-normanicone.