10377-60-3 Usage
Physical Properties
The anhydrous salt consists of white cubic crystals; density 2.3 g/cm3; very soluble in water. The dihydrate is white crystalline solid having density 1.45 g/cm3; decomposes at about 100°C; soluble in water and ethanol. The hexahydrate, MgNO3?6H2O is a colorless solid having monoclinic crystal structure and density 1.46 g/cm3. The salt is hygroscopic and very soluble in water and moderately soluble in ethanol.
Occurrence and Uses
The hexahydrate, Mg(NO3)2?6H2O, occurs in nature as mineral nitromagnesite. Magnesium nitrate is used in pyrotechnics; and in the manufacture of concentrated nitric acid to remove water and concentrate the acid vapors to 90–95% HNO3. It also is used to aid coating and prilling in production of ammonium nitrate. The salt also is used as an analytical standard for magnesium and a matrix modifier in furnace atomic absorption spectroscopic analysis. It also finds some limited application as a nitrogenous fertilizer.
Preparation
Different sources of media describe the Preparation of 10377-60-3 differently. You can refer to the following data:
1. Magnesium nitrate is prepared by the action of nitric acid on magnesium carbonate, oxide or hydroxide:
MgCO3 + 2HNO3 → Mg(NO3)2 + CO2 + H2O
Mg(OH)2 + 2HNO3 → Mg(NO3)2 + 2H2O
The salt crystallizing at room temperature after evaporation is the hexahydrate, Mg(NO3)2?2H2O.
2. The magnesium nitrate used in commerce has been synthesized in a variety of ways. The reaction between nitric acid and magnesium metal is one way and reaction with MgO is another. Magnesium hydroxide and ammonium nitrate also form the product but ammonia is released as a by-product: 2HNO3 + Mg Mg(NO3)2 +H2 2HNO3 + MgO Mg(NO3)2 +H2O Mg(OH)2 + 2NH4NO3 Mg(NO3)2 + 2NH3 + 2H2O Since magnesium nitrate has a high affinity for water, heating the hexahydrate does not result in the dehydration of the salt. Instead, it decomposes into magnesium oxide, oxygen and nitrogen oxides: 4Mg(NO3)2·6H2O + heat 4MgO + 2NO2 + 2N2O + O2 + 6H2O Heating the hexahydrate above its melting point first forms basic nitrates, such as Mg(NO3)2·4Mg(OH)2. It is this salt that decomposes at 400 C, forming magnesium oxide and oxides of nitrogen. The absorption of these nitrogen oxides in water is one possible way to synthesize HNO3. Although it is inefficient, it does not require the use of another strong acid and the mineral, nitromagnesite, can be used in this context.
Reactions
Thermal decomposition of anhydrous Mg(NO3)2 yields magnesium oxide and nitrogen oxides. Heating the hexahydrate above its melting point forms basic nitrates, such as Mg(NO3)2?4 Mg(OH)2. The latter decomposes at 400°C, forming magnesium oxide and oxides of nitrogen. Magnesium nitrate forms addition compounds with a number of nitrogen-containing organics such as pyridine, aniline, and urea.
Description
Magnesium nitrate has the molecular formula of
Mg(NO3)2 and the molecular weight of 148.3152 g/
mol.
Magnesium nitrate is prepared by the action of nitric
acid on magnesium carbonate, oxide or hydroxide:
MgCO3 + 2HNO3 ? Mg(NO3)2 + CO2 +H2O
Mg(OH)2 + 2HNO3 ? Mg(NO3)2 + 2H2O
The salt crystallizing at room temperature after
evaporation is the hexahydrate, Mg(NO3)2·6H2O. Two
stable hydrates are formed, the hexahydrate [CAS
number =13446-18-9] and the dihydrate, Mg(NO3)2·
2H2O [CAS number = 15750-45-5].
Chemical Properties
White crystals.Soluble in water and alcohol;
deliquescent.
Uses
Different sources of media describe the Uses of 10377-60-3 differently. You can refer to the following data:
1. In pyrotechnics; in the concentration of nitric acid.
2. It is used in printing, chemical, agriculture and ceramics industries. Its fertilizer grade has 10.5% nitrogen and 9.4% magnesium.
Definition
ChEBI: The inorganic nitrate salt of magnesium.
General Description
A white crystalline solid. Produces toxic oxides of nitrogen if heated to decomposition. Used in pyrotechnics.
Air & Water Reactions
Deliquescent. Water soluble.
Reactivity Profile
Mixtures of Magnesium nitrate with alkyl esters may explode owing to the formation of alkyl nitrates; mixtures with phosphorus, tin(II) chloride, or other reducing agents may react explosively [Bretherick 1979 p. 108-109]. Noncombustible but will accelerate the burning of combustible materials. If large quantities are involved in a fire or the combustible material is finely divided an explosion may result. Prolonged exposure to fire or heat may result in an explosion. Magnesium nitrate has been reported to undergo spontaneous decomposition in dimethylformamide [Bretherick 5th ed., 1995]. Magnesium nitrate tends to behave as a strong oxidizer.
Hazard
Dangerous fire and explosion risk in contact
with organic materials, strong oxidizing agent.
Health Hazard
Exposure can cause mild irritation to the mucous membranes. Symptoms may include coughing and shortness of breath. Ingestion of large doses may cause dizziness, abdominal pain, vomiting, bloody diarrhea, weakness, convulsions, and collapse. Contact with skin may cause irritation, redness, and pain.
Flammability and Explosibility
Nonflammable
Safety Profile
Probably a severe
irritant to the eyes, skin, and mucous
membranes. A powerful oxidizer. Violent
decomposition on contact with
dmethylformamide. When heated to
decomposition it emits toxic fumes of NOx.
See also NITRATES and MAGNESIUM
COMPOUNDS.
Check Digit Verification of cas no
The CAS Registry Mumber 10377-60-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,3,7 and 7 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 10377-60:
(7*1)+(6*0)+(5*3)+(4*7)+(3*7)+(2*6)+(1*0)=83
83 % 10 = 3
So 10377-60-3 is a valid CAS Registry Number.
InChI:InChI=1/Mg.NO3/c;2-1(3)4/q+2;-1
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